rongo

Ko te 1,3-Dichlorobenzene he wai karekau he haunga.Kare e rewa ki te wai, ka whakarewahia ki te waipiro me te etera.He paitini ki te tinana o te tangata, ka whakaparahako ki nga kanohi me te kiri.He muramura, ka taea te whakamaarama, te whakamaaramatanga, te whakangao-ahuru, me nga tauhohenga hauwai.He kaha te mahi ki te konumohe, ka whakamahia ki te whakahiato waro.

1. Āhuatanga: te wai kārekau he haunga.
2. Ira whakarewa (℃): -24.8
3. Ira kohua (℃): 173
4. Kiato whanaunga (wai = 1): 1.29
5. Te kiato kohu (rangi=1): 5.08
6. Te pēhanga kohu kukū (kPa): 0.13 (12.1 ℃)
7. Te wera o te ngingiha (kJ/mol): -2952.9
8. Te pāmahana tino nui (℃): 415.3
9. Te pehanga nui (MPa): 4.86
10. Te tauwehenga wehenga o te Octanol/wai: 3.53
11. Ira hiko (℃): 72
12. Te pāmahana whakakā (℃): 647
13. Te rohe pahū o runga (%): 7.8
14. Te rohe pahū raro (%): 1.8
15. Te whakarewatanga: kare e rewa ki te wai, ka whakarewahia ki te waiwaro me te etera, me te ngawari ki te acetone.
16. Viscosity (mPa·s, 23.3ºC): 1.0450
17. Ira mura (ºC): 648
18. Te wera o te whakaetonga (KJ/mol, bp): 38.64
19. Te wera o te hanga (KJ/mol, 25ºC, wai): 20.47
20. Te wera wera (KJ/mol, 25ºC, wai): 2957.72
21. Te kaha wera motuhake (KJ/(kg·K), 0ºC, wai): 1.13
22. Wairewa (%, wai, 20ºC): 0.0111
23. Kiato whanaunga (25℃, 4℃): 1.2828
24. Taupū whakaahuru noa (n25): 1.5434
25. Tawhā whakarewa (J·cm-3) 0.5: 19.574
26. Te horahanga o Van der Waals (cm2·mol-1): 8.220×109
27. rōrahi Van der Waals (cm3·mol-1): 87.300
28. Ko te paerewa wahanga wai e kii ana i te wera (enthalpy) (kJ·mol-1): -20.7
29. Wāhanga wai rewa wera paerewa (J·mol-1·K-1): 170.9
30. Ko te paerewa wahanga hau e kii ana i te wera (enthalpy) (kJ·mol-1): 25.7
31. Entropy paerewa o te wahanga hau (J·mol-1·K-1): 343.64
32. Paerewa pūngao korekore o te hanga i te wahanga hau (kJ·mol-1): 78.0
33. Whakarewa wera paerewa wahanga hau (J·mol-1·K-1): 113.90

Tikanga rokiroki
Whakatupato mo te rokiroki [Pokohia i roto i te whare putunga hauhautanga, whai hau.Kia matara atu i te ahi me nga puna wera.Kia kati te ipu.Me penapena motuhake mai i nga waiora, konumohe, me nga matū kai, me te karo i te rokiroki whakauru.Kua rite ki nga momo momo me te maha o nga taputapu ahi.Ko te waahi rokiroki me whakauru ki nga taputapu maimoatanga ohorere pakaru me nga taonga rokiroki tika.

Whakatau taumira:

Ko nga tikanga whakarite e whai ake nei.Ma te whakamahi i te chlorobenzene hei rauemi mata mo te whakamaarama ano, ka whiwhihia te p-dichlorobenzene, te o-dichlorobenzene me te m-dichlorobenzene.Ko te tikanga wehenga whanui e whakamahi ana i te dichlorobenzene whakauru mo te whakamarumaru tonu.Ko te para- me te meta-dichlorobenzene ka whakamarohia mai i te tihi o te pourewa, ka whakahekehia te p-dichlorobenzene ma te tio me te tioata, ka whakatikahia te waipiro whaea kia whiwhi meta-dichlorobenzene.Ko te o-dichlorobenzene he uira maturu i roto i te pourewa uira kia whiwhi o-dichlorobenzene.I tenei wa, ka whakamahia e te dichlorobenzene whakauru te tikanga o te adsorption me te wehenga, ma te whakamahi i te tatari molecular rite te adsorbent, me te wahanga hau i konatunatua ki te dichlorobenzene ka uru ki te pourewa adsorption, ka taea te whiriwhiri i te p-dichlorobenzene, a ko te toenga wai ko te meta me te ortho dichlorobenzene.Whakatikatika kia whiwhi m-dichlorobenzene me te o-dichlorobenzene.Ko 180-200°C te pāmahana adsorption, a ko te pēhanga adsorption he pēhanga noa.

1. Meta-phenylenediamine tikanga diazotization: Meta-phenylenediamine diazotized i roto i te aroaro o te konutai nitrite me te waikawa pungatara, te pāmahana diazotization ko 0~5 ℃, a ka hydrolyzed te wai diazonium ki te aroaro o te cuprous pūhaumāota ki te whakaputa intercalation.Dichlorobenzene.

2. Tikanga Meta-chloroaniline: Ma te whakamahi i te meta-chloroaniline hei rauemi mata, ka mahia te diazotization i te aroaro o te konutai nitrite me te waikawa waikawa, a ka whakamarohia te wai diazonium i te aroaro o te cuprous chloride ki te whakaputa meta-dichlorobenzene.

I roto i nga tikanga whakareri i runga ake nei, ko te tikanga tino pai mo te mahi ahumahi me te utu iti ko te tikanga whakawehe adsorption o te dichlorobenzene whakauru.He whare hanga kei Haina mo te whakaputa.

Ko te kaupapa matua:

1. Ka whakamahia i roto i te whakahiato waro.Ko te tauhohenga Friedel-Crafts i waenga i te m-dichlorobenzene me te chloroacetyl chloride ka puta te 2,4,ω-trichloroacetophenone, e whakamahia ana hei takawaenga mo te miconazole tarukino antifungal whanui.Ko te tauhohenga chlorination ka mahia i te aroaro o te ferric chloride me te konumohe mercury, te nuinga o te whakaputa 1,2,4-trichlorobenzene.I roto i te aroaro o te whakakōkī, ka hydrolyzed i te 550-850°C ki te whakaputa m-chlorophenol me resorcinol.Ma te whakamahi i te waikura parahi hei whakakorikori, ka tauhohe ki te haukini i te 150-200°C i raro i te pehanga ki te whakaputa m-phenylenediamine.
2. Ka whakamahia ki te hanga waikano, nga takawaenga whakahiato waro me te whakarewa.

Raraunga paitini:

1. Te paitini whakapeka: kiore intraperitoneal LD50: 1062mg/kg, kaore he korero engari mo te horopeta whakamate;

2. Raraunga paitini-maha-maha: kiore waha TDLo: 1470 mg/kg/10D-I, huringa taumaha ate-ate, paunga matūkai katoa, aukati konupūmā-enzyme, huringa whakaawe, huringa ranei i roto i te toto, i nga taumata kiko-phosphatase ;

TDLo-waha kiore: 3330mg/kg/90D-I, huringa endocrine, huringa i roto i nga wahanga toto-serum (pēnei i te polyphenols tea, bilirubin, cholesterol), te aukati matū-koiora, te whakakorikori, te huri ranei i nga taumata o te toto, te kiko ranei-dehydrogenation Te huringa Enzyme

3. Raraunga Mutagenicity: te hurihanga ira me te mitosis recombinationTEST system: Yast-Saccharomyces cerevisiae: 5ppm;

Te whakamātautau Micronucleus Pūnaha IntraperitonealTEST: kiore-kiore: 175mg/kg/24H.

4. He iti ake te paitini i tera o te o-dichlorobenzene, ka uru ki roto i te kiri me nga kiri mucous.Ka kino te ate me te whatukuhu.He 0.2mg/L te kukū o te paepae kakara (kounga wai).

5. Paitini whakapeka LD50: 1062mg/kg (kiore kiore);1062mg/kg (kohao puku kiore)

6. Irritant Karekau he korero

7. Te hurihanga ira mutagenic me te whakakotahitanga mitotic: Saccharomyces cerevisiae 5ppm.Whakamātautau Micronucleus: whakahaere intraperitoneal o 175mg/kg (24h) i roto i te kiore

8. Carcinogenicity IARC carcinogenicity arotake: Rōpū 3, kaore e taea e nga taunakitanga o naianei te whakarōpū i te mate mate tangata.


Te wa tuku: Hanuere-28-2021